110452-48-7

Basic information

• Product Name: Meso-Tetra(4-tert-butylphenyl) Porphine
• Synonyms: Meso-Tetra(4-tert-butylphenyl) Porphine;4-tert-Bu-TPP;5,10,15,20-tetra(4-tert-butyl-phenyl)porphyrin;5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphine;5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin;5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin;free base 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphine;meso-tetrakis(4-tert-butylphenyl)porphyrin
• CAS NO: 110452-48-7
• Molecular Formula: C₆₀H₆₂N₄
• Molecular Weight: 839.16108
• Mol File: 110452-48-7.mol

Chemical Properties

• Appearance: /
• Density: 1.108g/cm³
• Refractive Index: 1.61
• CAS DataBase Reference: Meso-Tetra(4-tert-butylphenyl) Porphine(CAS DataBase Reference)
• NIST Chemistry Reference: Meso-Tetra(4-tert-butylphenyl) Porphine(110452-48-7)
• EPA Substance Registry System: Meso-Tetra(4-tert-butylphenyl) Porphine(110452-48-7)

Safety Data

• Hazardous Substances Data: 110452-48-7(Hazardous Substances Data)

Usage

Uses

Used in Photo-induced Charge Separation Studies:
Meso-Tetra(4-tert-butylphenyl) Porphine is used as a photosensitizer for photo-induced charge separation studies. Its ability to absorb light and generate charge-separated states makes it a valuable compound for understanding and improving the efficiency of charge separation processes in various applications, such as solar energy conversion and photocatalysis.
Used in the Preparation of Porphyrin Naphthalocyanine Double-layer Metal Complex:
Meso-Tetra(4-tert-butylphenyl) Porphine is utilized as a key component in the synthesis of Porphyrin Naphthalocyanine double-layer metal complexes. These complexes exhibit unique optical and electronic properties, which can be exploited in various applications, such as optoelectronics and sensing technologies.
Used in Detection of Low-concentration Acetone in the Environment:
Meso-Tetra(4-tert-butylphenyl) Porphine is employed as a sensing material for the detection of low-concentration acetone in the environment. Its high sensitivity and selectivity towards acetone make it a promising candidate for developing highly efficient and accurate sensors for environmental monitoring and industrial applications.

InChI:InChI=1/C60H62N4/c1-57(2,3)41-21-13-37(14-22-41)53-45-29-31-47(61-45)54(38-15-23-42(24-16-38)58(4,5)6)49-33-35-51(63-49)56(40-19-27-44(28-20-40)60(10,11)12)52-36-34-50(64-52)55(48-32-30-46(53)62-48)39-17-25-43(26-18-39)59(7,8)9/h13-36,61,64H,1-12H3/b53-45-,53-46-,54-47-,54-49-,55-48-,55-50-,56-51-,56-52-

Upstream product

• 939-97-9 4-tert-Butylbenzaldehyde 
• 167482-99-7 5-(4-carbomethoxyphenyl)dipyrromethane 
• 1571-08-0 methyl 4-formylbenzoate 
• 167482-98-6 2,2′-((4-(tert-butyl)phenyl)methylene)bis(1H-pyrrole) 
• 109-97-7 pyrrole 
• 158399-19-0 4-formyl-5-methoxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthene 
• 33795-37-8 1,10-phenanthroline-2-carboxyaldehyde 
• 555-16-8 4-nitrobenzaldehdye 
• 371171-46-9 2,6-diacetamido-4-formylpyridine 
• 287969-17-9 4-t-butyl-2,6-bis(methoxymethyl)phenyl-dipyrromethane 
• 105-07-7 4-cyanobenzaldehyde 

Downstream Products

• 213481-27-7 5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrinato nickel(II) 
• 118589-15-4 C₆₀H₆₀N₄Zn 
• 108175-63-9 (5,10,15,20-tetra(4-tert-butylphenyl)-21H,23H-porphinato)cobalt(II) 
• 110329-59-4 [5,10,15,20-tetrakis(4-tert-butylphenyl)porphyrinato]copper(II) 
• 1358953-91-9 Zn(II) 2,3,12,13-tetrabromo-5,10,15,20-tetrakis-(4-t-butylphenyl)porphyrin 
• 643768-37-0 [5,10,15,20-tetrakis(4-tert-butylphenyl)porphyrinato]platinum(II) 
• 187801-62-3 [5,10,15,20-tetrakis(4-tert-butylphenyl)porphyrinato]ruthenium(II)carbonyl 

Relevant articles and documents

Synthesis of meso substituted porphyrins in air without solvents or catalysts

meso-Tetraarylporphyrins are synthesized from pyrrole and aryl aldehydes cleanly and efficiently in one step without solvents or catalysts by reactions at temperatures 10-15°C above the boiling point of the starting aldehydes using air as oxidant.

Synthesis of new azido porphyrins and their reactivity in copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition reaction with alkynes

We report herein the preparation of two novel porphyrins substituted with an azido group born either on the para-position of one phenyl meso-susbtituent of a tetraaryl zinc porphyrin (1) or directly on the meso-position of a trisaryl nickel porphyrin (2).

Photocatalytic CO2 Reduction Mediated by Electron Transfer via the Excited Triplet State of Zn(II) Porphyrin

A porphyrin/rhenium complex dyad, ZnP-phen=Re, in which the 2-position of the 1,10-phenanthroline (phen) of fac-Re(phen)(CO)3Br is directly connected with the meso-position of zinc(II) porphyrin, showed phosphorescence from the zinc porphyrin part under Ar, even at room temperature. The phosphorescence was efficiently quenched by 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole (BIH) used as an electron donor, under Ar, with the Stern-Volmer constant KSV = 180a?000 M-1, indicating that the quantitative photoinduced electron transfer occurred from BIH to the excited triplet state (T1) of ZnP-phen=Re. The system affords CO with a high turnover number (>1300) and >99.9% CO selectivity in the photocatalytic CO2 reduction.

Design and synthesis of porphyrins bearing rigid hydrogen bonding motifs: Highly versatile building blocks for self-assembly of polymers and discrete arrays

Two aldehydes, 2,6-diacetamido-4-formylpyridine (7) and 1-butyl-6-formyluracil (11), are used to synthesize five pyridyl and four uracyl meso-subsituted porphyrins. With these complementary porphyrin building blocks, it is possible to build various types of multi-porphyrin supramolecules with different spatial relationships in predefined geometries. The formation and properties of self-complementary dimers and a dosed tetrameric square are presented as a basis of comparison to the latter system in the solid state. An X-ray structure of 5,10-bis(4-tert-butylphenyl)-15,20-bis-(3,5-diacetamido-4-pyridyl)porphyrin confirms its molecular structure and reveals a hydrogen-bonded supramolecular organization mediated by water molecules.

Oxidative Cyclodehydrogenation Reactions with Tetraarylporphyrins

The extension of the aromatic π-system of porphyrins is a powerful method to alter their optoelectronic properties. Herein, aryl substituents were fused to porphyrin cores by Scholl oxidation reactions that selectively produced mono- and doubly-fused porphyrins in yields of up to 69 %. Several different aryl substituents attached to the porphyrin were investigated with respect to their reactivity under Scholl conditions. The fused products were fully characterized, i.e., by UV/Vis absorption spectroscopy, which showed drastic changes in the electronic features. Insight into the solid-state behavior was obtained by X-ray crystallography. Our approach represents a novel option for the late-stage functionalization of porphyrin-based compounds.

PHOTOSENSITIVE RESIN COMPOSITION AND PHOTOSENSITIVE RESIN LAYER USING THE SAME, ADHESIVE COMPOSITION AND ADHESIVE FILM USING THE SAME, COLOR FILTER, POLARIZING PLATE AND OPTICAL DISPLAY DEVICE

The present invention is related to a photosensitive resin composition and an adhesive composition including a compound represented by Chemical Formula 1, a photosensitive resin layer and an adhesive film manufactured using the composition, a color filter

Formation Reaction and Chemical Structure of a Novel Supramolecular Triad Based on Cobalt(II) 5,10,15,20-(Tetra-4-Tert-Butylphenyl)-21Н,23Н-Porphyrin and 1-Methyl-2-(Pyridin-4′-Yl)- 3,4-Fullero[60]Pyrrolidine

Results of chemical kinetic/thermodynamic and spectroscopic studies of the reaction of cobalt(II) 5,10,15,20-(tetra-4-tert-butylphenyl)-21Н,23Н-porphyrin (CoIITBPP) with 1-methyl-2-(pyridin-4′-yl)-3,4- fullero[60]pyrrolidine (PyF) in toluene at

Facile synthesis of β-functionalized “push-pull” Zn(II) porphyrins for DSSC applications

Three new β-substituted “push-pull” Zn(II) porphyrin dyes with various electron donors at meso-positions and cyanoacetic acid as acceptor at β-position have been designed and synthesized. These porphyrins have been characterized by UV-Vis, Fluorescence,

Serial compounds with triptycene as framework and in bridge connection with metalloporphyrin through pyrene tetrone and preparation method therefor

The invention discloses serial compounds with triptycene as a framework and in bridge connection with metalloporphyrin through pyrene tetrone and a preparation method therefor, and belongs to the photoelectric conversion material field. The compound molec

METHODS AND COMPOSITIONS COMPRISING MACROCYCLES

The present invention relates generally to methods and compositions comprising macrocycles. In some embodiments, the present invention provides methods for modifying macrocycles comprising a pendant group. In some cases, the pendent group comprises a hydrolyzable group. The present invention also provides methods for metallating a macrocycle using microwave energy, in some embodiments.