Conformational Preference in 1,3-Dithianes Containing 2-Phosphoryl, -(thiophosphoryl), and -(selenophosphoryl) groups. Chemical and Crystallographic Implications of the Nature of the Anomeric Effect
The operation of anomeric effect in all the title compounds studied was found.The magnitude of the anomeric effect was found to be larger than 10 kJ/mol.Crystallographic, spectroscopic, and thermodynamic data suggest that nS-?*C
Mikolajczyk, Marian,Graczyk, Piotr P.,Wieczorek, Michal W.
p. 1672 - 1693
(2007/10/02)
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