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110677-96-8

1-cyclohexene carboxaldehyde cyclic (1S,2S)-1,2-bis<(benzyloxy)methyl>ethylene acetal is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 110677-96-8 Structure

  • Basic information

    1. Product Name: 1-cyclohexene carboxaldehyde cyclic (1S,2S)-1,2-bis<(benzyloxy)methyl>ethylene acetal
    2. Synonyms: 1-cyclohexene carboxaldehyde cyclic (1S,2S)-1,2-bis<(benzyloxy)methyl>ethylene acetal
    3. CAS NO:110677-96-8
    4. Molecular Formula:
    5. Molecular Weight: 394.511
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 110677-96-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1-cyclohexene carboxaldehyde cyclic (1S,2S)-1,2-bis<(benzyloxy)methyl>ethylene acetal(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1-cyclohexene carboxaldehyde cyclic (1S,2S)-1,2-bis<(benzyloxy)methyl>ethylene acetal(110677-96-8)
    11. EPA Substance Registry System: 1-cyclohexene carboxaldehyde cyclic (1S,2S)-1,2-bis<(benzyloxy)methyl>ethylene acetal(110677-96-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 110677-96-8(Hazardous Substances Data)

110677-96-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 110677-96-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,0,6,7 and 7 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 110677-96:
(8*1)+(7*1)+(6*0)+(5*6)+(4*7)+(3*7)+(2*9)+(1*6)=118
118 % 10 = 8
So 110677-96-8 is a valid CAS Registry Number.

110677-96-8Relevant articles and documents

HOMOCHIRAL KETALS IN ORGANIC SYNTHESIS. DIASTEREOSELECTIVE CYCLOPROPANATION OF α,β-UNSATURATED KETALS DERIVED FROM 1,4-Di-O-BENZYL-L-THREITOL

Mash, Eugene A.,Nelson, Keith A.

, p. 679 - 692 (2007/10/02)

2-Cykloalken-1-one 1,4-di-O-benzyl-L-threitol ketals undergo efficient and diastereoselective cyclopropanation when treated with an excess of the Simmons-Smith reagent.For example, 2-cyclohexen-1-one 1,4-di-O-benzyl-L-threitol ketal gave in 90-98percent yield a 9:1 mixture of diastereomeric cyclopropanes as established by 62.9 MHz 13C NMR spectroscopy and by hydrolysis of the mixture to (1R,6S)-bicycloheptan-2-one.Sixteen other examples are presented which demonstrate the generality and predictability of the process for 2-cycloalken-1-one ketals, as well as an unfortunate lack of diastereoselectivity for α,β-unsaturated 1,4-di-O-benzyl-L-threitol acetals.

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