Synthesis of Triphenylene 1,2-Oxide (1,2-Epoxy-1,2-dihydrophenylene) and Absolute Configuration of the trans-1,2-Dihydro Diol Metabolite of Triphenylene. Crystal Structure of (-)-(1R,2R)-trans-2-Bromo-1-menthyloxyacetoxy-1,2,3,4-tetrahydrotriphenylene
The synthesis of triphenylene 1,2-oxide (1,2-epoxy-1,2-dihydrotriphenylene) (2) from both racemic and optically pure precursors is reported.Racemic triphenylene 1,2-oxide (2) was obtained in each case, in accord with PMO calculations which predict rapid r
Boyd, Derek R.,Kennedy, Deirdre A.,Malone, John F.,O'Kaine, Gerard A.
p. 369 - 376
(2007/10/02)
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