Organocatalytic asymmetric syn-aldol reactions of aldehydes with long-chain aliphatic ketones on Water and with dihydroxyacetone in organic solvents
An on-water, asymmetric, and direct synaldol reaction of aliphatic ketones with aromatic aldehydes catalyzed by a primary amino acid-based organocatalyst afforded the syn-aldol adducts in high yields with excellent diastereo- and enantioselectivities (up
Zhu, Ming-Kui,Xu, Xiao-Ying,Gong, Liu-Zhu
supporting information; experimental part
p. 1390 - 1396
(2009/05/30)
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