Sterically Crowded Sulfonate Esters: Novel Leaving Groups with Hindered S-O Cleavage
Reagents and procedures for the preparation of tert-butyl sulfonate esters 2 and 2,2,2-trifluoro-1,1-diphenylethane sulfonate esters 3 (TDE-sulfonates) are described.In these new sulfonates, S-O-scission is reduced significantly by steric hindrance.
Netscher, Thomas,Prinzbach, Horst
p. 683 - 688
(2007/10/02)
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