Oxidation of an αβ-(epoxyalkyl) trimethylsilane with pyridine oxides in the presence of silylating agents. A facile enantioselective synthesis of glyceraldehyde derivatives
Trimethylsilyl glycidol derivatives 1 were oxidized with pyridine N-oxides in the presence of silylating agents to give the corresponding glyceraldehyde derivatives 3. Reaction of (α,β-epoxyalkyl)silanes with N-oxides was studied.
Raubo, Piotr,Wicha, Jerzy
p. 3387 - 3390
(2007/10/02)
The mechanism of the formation of silyl enol ethers from hydrosilanes and organic carbonyl compounds in the presence of cobalt carbonyls. Kinetic investigation of some reaction steps
The cleavage of isobutyrylcobalt tetracarbonyl with triethylsilane gives (triethylsilyl)cobalt tetracarbonyl, isobutyraldehyde, dicobalt octacarbonyl, and the corresponding unsaturated and saturated silyl ethers. Silyl enol ether was also formed, along wi
Kovács, István,Sisak, Attila,Ungváry, Ferenc,Markó, László
p. 1025 - 1028
(2008/10/08)
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