1133-81-9

Basic information

• Product Name: naphthalen-1-yl carbamate
• Synonyms: 1-Naphthalenol, carbamate
• CAS NO: 1133-81-9
• Molecular Formula: C₁₁H₉NO₂
• Molecular Weight: 187.1947
• Mol File: 1133-81-9.mol

Chemical Properties

• Boiling Point: 392.2°C at 760 mmHg
• Flash Point: 225.5°C
• Density: 1.261g/cm³
• Vapor Pressure: 2.32E-06mmHg at 25°C
• Refractive Index: 1.653
• CAS DataBase Reference: naphthalen-1-yl carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: naphthalen-1-yl carbamate(1133-81-9)
• EPA Substance Registry System: naphthalen-1-yl carbamate(1133-81-9)

Safety Data

• Hazardous Substances Data: 1133-81-9(Hazardous Substances Data)

Upstream product

• 463-72-9 carbamic chloride 
• 90-15-3 α-naphthol 
• 1130-90-1 1-naphthyl cyanate 
• 3759-61-3 1-naphthyl chloroformate 
• 917-61-3 sodium isocyanate 
• 86-84-0 1-Naphthyl isocyanate 
• 590-28-3 potassium cyanate 
• 57-13-6 urea 

Downstream Products

• 41142-24-9 (Naphthalen-1-yloxycarbonylamino)-(4-nitro-benzenesulfonyl)-acetic acid 

Relevant articles and documents

An efficient one-pot synthesis of industrially valuable primary organic carbamates and: N -substituted ureas by a reusable Merrifield anchored iron(ii)-anthra catalyst [FeII(Anthra-Merf)] using urea as a sustainable carbonylation source

An efficient synthesis of primary carbamates and N-substituted ureas is explored with a newly developed heterogeneous polymer supported iron catalyst in the presence of a sustainable carbonylation source. The Merrifield anchored iron(ii)-anthra catalyst [FeII(Anthra-Merf)] was synthesized by functionalization of Merrifield polymer followed by grafting of iron metal. The catalyst [FeII(Anthra-Merf)] was characterized by several techniques, like SEM, EDAX, TGA, PXRD, XPS, FTIR, CHN, AAS and UV-Vis analysis. The designed polymer embedded [FeII(Anthra-Merf)] complex is a remarkably successful catalyst for the synthesis of primary organic carbamates and N-substituted ureas by using safe carbonylation agent urea with different derivatives of alcohols and amines, respectively. The reported catalyst is a potential candidate towards contributing a satisfactory yield of isolated products under suitable reaction conditions. The catalyst is recyclable and almost non-leaching in nature after six runs with an insignificant drop in catalytic activity. Thus we found an economical and viable catalyst [FeII(Anthra-Merf)] for primary carbamates and N-substituted urea synthesis under moderate reaction conditions.

4-Dodecylbenzenesulfonic acid (DBSA) promoted solvent-free diversity-oriented synthesis of primary carbamates, S-thiocarbamates and ureas

A simple and highly efficient solvent-free method for the conversion of alcohols, phenols, thiols and amines to primary carbamates, S-thiocarbamates and ureas in the presence of 4-dodecylbenzenesulfonic acid (DBSA) as a cheap and green Bronsted acid reagent has been described. All products were obtained in good to excellent yields and characterized using FT-IR, 1H- and 13C-NMR, MS and CHNS techniques.

Silica supported perchloric acid (HClO4-SiO2): an efficient reagent for the preparation of primary carbamates under solvent-free conditions

The synthesis of primary carbamates from structurally diverse compounds containing a hydroxyl group has been performed in high yields and purity, and without any epimerization under solvent-free conditions using HClO4-SiO2 as a mild, convenient, and effective reagent. The procedure is operationally simple, efficient, and environmentally benign.

(2R*,3S*)-(E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol

(2R*,3S*)-(E)-3-Methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol possesses a very intense creamy, woody, musk, sandalwood odor and is a valuable ingredient for use in fragrance compositions for its musk and sandalwood-like qualities. This odorant is more intense than any of the campholenic aldehyde derivatives that have been previously reported.