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9-Fluorobenzo[k]fluoranthene is a polycyclic aromatic hydrocarbon and a fluorinated derivative of benzo[k]fluoranthene. It is characterized by its highly toxic and potentially carcinogenic nature, primarily formed through the incomplete combustion of organic materials such as coal, oil, and gas. Its molecular structure comprises four fused benzene rings with a fluorine atom attached at the 9th position, making it a persistent organic pollutant known for bioaccumulation in the environment and living organisms. Exposure to 9-fluorobenzo[k]fluoranthene has been linked to various adverse health effects, including developmental and reproductive toxicity, as well as potential carcinogenicity. As a result, it is regulated and monitored in environmental and occupational settings to reduce human and ecological exposure.

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  • 113600-15-0 Structure
  • Basic information

    1. Product Name: 9-FLUOROBENZO[K]FLUORANTHENE
    2. Synonyms: 9-FLUOROBENZO[K]FLUORANTHENE;9-fluoro-benzo(k)fluoranthen
    3. CAS NO:113600-15-0
    4. Molecular Formula: C20H11F
    5. Molecular Weight: 270.3
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 113600-15-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 470.4 °C at 760 mmHg
    3. Flash Point: 203.5 °C
    4. Appearance: /
    5. Density: 1.349 g/cm3
    6. Vapor Pressure: 1.44E-08mmHg at 25°C
    7. Refractive Index: 1.86
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 9-FLUOROBENZO[K]FLUORANTHENE(CAS DataBase Reference)
    11. NIST Chemistry Reference: 9-FLUOROBENZO[K]FLUORANTHENE(113600-15-0)
    12. EPA Substance Registry System: 9-FLUOROBENZO[K]FLUORANTHENE(113600-15-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 113600-15-0(Hazardous Substances Data)

113600-15-0 Usage

Uses

Due to the highly toxic and potentially carcinogenic nature of 9-fluorobenzo[k]fluoranthene, its direct use in applications is limited. However, it may be encountered in the following industries and applications:
Used in Environmental Monitoring and Research:
9-Fluorobenzo[k]fluoranthene is used as a target analyte for environmental monitoring and research purposes to assess the levels of this pollutant in air, water, soil, and living organisms. Monitoring its presence helps in understanding the extent of environmental contamination and the potential risks to human health and ecosystems.
Used in Occupational Health and Safety:
In industries where the incomplete combustion of organic materials occurs, such as coal, oil, and gas production, 9-fluorobenzo[k]fluoranthene is used as a parameter for assessing occupational exposure to this hazardous compound. Regular monitoring and control measures are implemented to minimize workers' exposure and protect their health.
Used in Toxicology and Risk Assessment Studies:
9-Fluorobenzo[k]fluoranthene serves as a model compound in toxicology and risk assessment studies to investigate its adverse health effects, including developmental and reproductive toxicity, as well as potential carcinogenicity. These studies contribute to the development of regulations, guidelines, and preventive measures to mitigate the risks associated with exposure to this chemical.

Check Digit Verification of cas no

The CAS Registry Mumber 113600-15-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,3,6,0 and 0 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 113600-15:
(8*1)+(7*1)+(6*3)+(5*6)+(4*0)+(3*0)+(2*1)+(1*5)=70
70 % 10 = 0
So 113600-15-0 is a valid CAS Registry Number.
InChI:InChI=1/C20H11F/c21-15-8-7-13-10-18-16-5-1-3-12-4-2-6-17(20(12)16)19(18)11-14(13)9-15/h1-11H

113600-15-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 9-FLUOROBENZO[K]FLUORANTHENE

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:113600-15-0 SDS

113600-15-0Downstream Products

113600-15-0Relevant articles and documents

Synthesis of Fluorinated Derivatives of Benzofluoranthene and Indenopyrene and 8,9-dihydro-8,9-epoxybenzofluoranthene

Rice, Joseph E.,Czech, Anna,Hussain, Nalband,LaVoie, Edmond J.

, p. 1775 - 1779 (2007/10/02)

The synthesis of several select fluorinated derivatives of benzofluoranthene and indenopyrene is described.In the benzofluoranthene series, the 8- and 9-fluoro derivatives have been prepared by Wittig reaction of the 1,2-bis salt of the appropriate fluorobenzene with acenaphthenequinone under phase-transfer conditions.The synthesis of 2-fluoroindenopyrene was achieved by photocyclization of 1-(β,β-difluorovinyl)benzofluoranthene followed by dehydrofluorination in methanolic sodium methoxide.This represents a new method for the construction of the indenopyrene skeleton. 8,9-Difluoroindenopyrene was prepared from 1-(2-amino-4,5-diflurophenyl)pyrene by diazotization followed by coupling in the presence of copper-bronze.In addition to these fluorinated derivatives, the synthesis of 8,9-dihydro-8,9-epoxybenzofluoranthene, a suspect ultimate tumorigenic metabolite of benzofluoranthene, is reported.This arene oxide was prepared from the trans-8,9-bromo acetate by benzylic bromination and subsequent treatment with sodium methoxide in anhydrous THF.

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