113850-15-0Relevant articles and documents
Collisional reaction of liquid droplets: Amidation of dansyl chloride observed by fluorescence enhancement
Suzuki, Tomoko,Kohno, Jun-Ya
, p. 1575 - 1577 (2015)
The collisional reaction of droplets is observed by time-resolved fluorescence spectroscopy. Colliding droplets of the reactant solutions are irradiated with a pulsed laser, and the resulting fluorescence spectra and images of the colliding droplets are observed as a function of the elapsed time from the collision. The amidation reaction of dansyl chloride with isopropylamine is observed through fluorescence enhancement on a microsecond time scale. The present method enables us to measure the early stages of reactions in solutions.
Functionalization of α-C(sp3)?H Bonds in Amides Using Radical Translocating Arylating Groups
Radhoff, Niklas,Studer, Armido
supporting information, p. 3561 - 3565 (2021/01/04)
α-C?H arylation of N-alkylamides using 2-iodoarylsulfonyl radical translocating arylating (RTA) groups is reported. The method allows the construction of α-quaternary carbon centers in amides. Various mono- and disubstituted RTA-groups are applied to the arylation of primary, secondary, and tertiary α-C(sp3)?H-bonds. These radical transformations proceed in good to excellent yields and the cascades comprise a 1,6-hydrogen atom transfer, followed by a 1,4-aryl migration with subsequent SO2 extrusion.
Combinatorial dansyl library and its applications to pH-responsive probes
Hong, Seong Cheol,Murale, Dhiraj P.,Lee, Jun-Seok
, p. 347 - 352 (2016/07/06)
Herein, we report the first 48-membered, dansyl-based, combinatorial fluorescent library. From the electronic and structural properties of the probes, we analyzed their optical properties and chemical yields, with an average of 49 %. The molecules were ex