113985-41-4Relevant articles and documents
Palladium-catalyzed dearomative cyclocarbonylation of allyl alcohol for the synthesis of quinolizinones
Xu, Pengcheng,Qian, Bo,Qi, Zaojuan,Gao, Bao,Hu, Bin,Huang, Hanmin
, p. 1274 - 1277 (2021)
An approach for the synthesis of quinolizinone with potential bioactivity has been developedviapalladium-catalytic dearomative cyclocarbonylation of allyl alcohol. Diverse quinolizinone compounds could be attained with good efficiencies. A feasible reaction pathway could be a successive procedure of allylation, dearomatization, CO insertion and the Heck reaction.
Synthese regioselective par voie organometallique de pyridines, 4-picolines et 3,5-lutidines substituees en 2 par un groupe insature et/ou fonctionnel
Al-Arnaout, A.,Courtois, G.,Miginiac, L.
, p. 139 - 154 (2007/10/02)
A regioselective one-pot synthesis of 2-substituted pyridine derivatives from N-alkoxycarboxylpyridinium salts and α-unsaturated organozinc compounds is described.Similarly, functional alkynyl organomagnesium compounds lead to 2-alkynyl-ω-functional pyridines, from which (E)-2-alkenyl or 2-alkyl-ω-functional pyridines can be obtained by partial or complete reduction.
