114095-72-6

Basic information

• Product Name: ACETIC ACID 1-(3-METHOXY-PHENYL)-BUT-3-ENYL ESTER
• Synonyms: ACETIC ACID 1-(3-METHOXY-PHENYL)-BUT-3-ENYL ESTER
• CAS NO: 114095-72-6
• Molecular Formula: C₁₃H₁₆O₃
• Molecular Weight: 220.26434
• Mol File: 114095-72-6.mol

Chemical Properties

• Boiling Point: 301.8±37.0 °C(Predicted)
• Appearance: /
• Density: 1.040±0.06 g/cm3(Predicted)
• CAS DataBase Reference: ACETIC ACID 1-(3-METHOXY-PHENYL)-BUT-3-ENYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 1-(3-METHOXY-PHENYL)-BUT-3-ENYL ESTER(114095-72-6)
• EPA Substance Registry System: ACETIC ACID 1-(3-METHOXY-PHENYL)-BUT-3-ENYL ESTER(114095-72-6)

Safety Data

• Hazardous Substances Data: 114095-72-6(Hazardous Substances Data)

Upstream product

• 24165-65-9 1-(3-methoxyphenyl)but-3-en-1-ol 
• 108-24-7 acetic anhydride 
• 591-31-1 3-methoxy-benzaldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 106-95-6 allyl bromide 
• 59184-17-7 1,1-diacetoxy-1-(3-methoxyphenyl)methane 

Relevant articles and documents

Sc(OTf)3, an efficient catalyst for addition of allyltrimethysilane to aldehydes: Chemoselective addition to aldehydes in presence of ketone and in situ acylation (3-component coupling)

Scandium triflate (2-10 mol%) have been found to be a highly efficient catalyst for the addition of allyltrimethylsilane to both activated aromatic and aliphatic aldehydes. However, deactivated (electron rich) aromatic aldehydes gave double allylated products instead. Using a stoichiometric amount of Ac2O in the allylation reaction led directly to homoallylic acetates [in situ acylation catalysed by Sc(OTf)3] and for the first time gave high yields of adducts with moderately electron rich aromatic aldehydes.

Scandium triflate catalyzed allylation of acetals and gem-diacetates: A facile synthesis of homoallyl ethers and acetates

Scandium triflate catalyzes efficiently the allylation reactions of acetals and gem-diacetates with allyltrimethylsilane at ambient temperature to afford the corresponding homoallyl ethers and acetates in high yields. Also it is found to be effective for

Indium-mediated one-pot, three-component synthesis of homoallyl alcohol esters without catalysts and dehydrants

Indium-mediated one-pot esterification reaction of acyl chlorides or anhydride by using in situ-prepared homoallyl alcohols from aromatic aldehydes and allyl bromide proceeded smoothly to afford the corresponding homoallyl alcohol esters in high yields within about 1 h, which provided a simple and efficient protocol for the simultaneous allylation and esterification of aldehydes without other catalysts and dehydrants.

Bismuth compounds in organic synthesis. A one-pot synthesis of homoallyl ethers and homoallyl acetates from aldehydes catalyzed by bismuth triflate

(Chemical Equation Presented) Three one-pot methods for the conversion of aldehydes to homoallyl ethers catalyzed by Bi(OTf)3? xH 2O (1 x 4) have been developed. The one-pot synthesis of homoallyl ethers can be achieved either by

ARYLCYCLOPROPANE PHOTOCHEMISTRY. UNUSUAL AROMATIC SUBSTITUENT EFFECTS ON THE PHOTOCHEMICAL REARRANGEMENT OF (2-ARYLCYCLOPROPYL)METHYL ACETATES TO 1-ARYLHOMOALLYL ACETATES.

Irradiation of trans(2-arylcyclopropyl)methyl acetates a 4-butenyl-1-arylacetate (7a,b,d-h) via an ionic mechanism from the singlet state. Similar rearrangements occurred with exo-(1,1a,6,6a-tetrahydrocycloprop left bracket a right bracket inden-1-yl)methyl acetate and the 4-cyano derivative. Excited state reaction rate constants were determined from reactant fluorescence lifetimes and product quantum yields. It is concluded that the rate-determining step involves conversion of the initially formed aromatic excited state to a reactive cyclopropane excited state and that cyclopropane to aromatic ring charge transfer enhances this process.