HIGH DIASTEREOSELECTIVITY OBSERVED IN THE VINYLATION REACTION OF α,β-EPOXY ALDEHYDES WITH β-SILYLPHOSPHOROUS YLIDE
The high erythro diastereofacial selectivities were observed in the silyl group migrative vinylation of α,β-epoxy aldehydes substituted by an alkyl or silyl group at the β-position using 2-diphenylmethylsilylethylidene-tris(4-methoxyphenyl)phosphorane.
Iio, Hideo,Mizobuchi, Tsukasa,Tokoroyama, Takashi
p. 2379 - 2382
(2007/10/02)
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