A copper-catalyzed, pH-neutral construction of high-enantiopurity peptidyl ketones from peptidic S-acylthiosalicylamides in air at room temperature
A copper-catalyzed transformation of peptidic thiol esters and boronic acids gives peptidyl ketones and takes place in DMF or DMF/H2O at room temperature in air (see scheme). This aerobic reaction only occurs at a thiol ester group capable of coordinating
Liebeskind, Lanny S.,Yang, Hao,Li, Hao
supporting information; experimental part
p. 1417 - 1421
(2009/07/18)
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