114601-85-3 Usage
Check Digit Verification of cas no
The CAS Registry Mumber 114601-85-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,6,0 and 1 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 114601-85:
(8*1)+(7*1)+(6*4)+(5*6)+(4*0)+(3*1)+(2*8)+(1*5)=93
93 % 10 = 3
So 114601-85-3 is a valid CAS Registry Number.
InChI:InChI=1/C20H30O4/c1-3-4-5-6-7-11-14-19(17(2)22)18(16-21)13-10-8-9-12-15-20(23)24/h7-8,10-11,14,16,18H,3-6,9,12-13,15H2,1-2H3,(H,23,24)/b10-8+,11-7+,19-14+
114601-85-3Relevant articles and documents
DI-TERT-BUTYLMETHYLSILYL (DTBMS) TRIFLUOROMETHANESULFONATE. PREPARATION AND SYNTHETIC APPLICATIONS OF DTBMS ESTERS AND ENOL ETHERS
Bhide, Rajeev S.,Levison, Bruce S.,Sharma, Ram B.,Ghosh, Subrata,Salomon, Robert G.
, p. 671 - 674 (2007/10/02)
DTBMS triflate, readily available from dichloromethylsilane, provides carboxylic esters which resist reduction by hydridoaluminate or acid catalyzed hydrolysis, and vinylogous esters ( enol ethers of hydroxymethylene ketones ) which resist 1,4-addition of methyllithium.