Synthesis and properties of alkaline metal complexes with new overcrowded β-diketiminato ligands
Enaminoimines TbtNHC(Me)CHC(Me)NAr (5, Tbt = 2,4,6-[CH(SiMe3)2]3C6H2) bearing a Tbt group were synthesized by the two steps condensation of acetylacetone with bulky amines. Enaminoimines 5 were treate
2,4,6-Trisphenyl, a New Sterically Demanding Group for Kinetic Stabilization of Unstable Compounds
The titled group (Ar) has been found to be very efficient for kinetic stabilization of a highly reactive N-thiosulfinyl group.The synthesis and the thermal and photochemical behavior of Ar-N=S=s are described.
Okazaki, Renji,Unno, Masafumi,Inamoto, Naoki
p. 2293 - 2294
(2007/10/02)
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