New Gold Carbene Complexes via Carbene Transfer Reactions
Tungsten aryl- and alkylcarbene complexes on reaction with HAuCl4 give good yields of the corresponding gold carbene complexes (2a - e, 4).The reaction involves a redox process for which a mechanism is dicussed.The transfer of the carbene ligand proceeds by retention of its configuration.
Aumann, Rudolf,Fischer, Ernst Otto
p. 1853 - 1857
(2007/10/02)
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