An intramolecular titanium-catalyzed asymmetric Pauson - Khand type reaction
The development of the first catalytic asymmetric Pauson - Khand type cyclization of enynes is described. The active catalyst, (S,S)-(EBTHI)Ti(CO)2 (1), is generated in situ from (S,S)-(EBTHI)TiMe2 (2). A variety of 1,6-enynes can be
Hicks, Frederick A.,Buchwald, Stephen L.
p. 7026 - 7033
(2007/10/03)
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