Iron-mediated synthesis of carbazomycin G and carbazomycin H, the first carbazole-1,4-quinol alkaloids from Streptoverticillium ehimense
The total synthesis of the carbazole-1,4-quinol alkaloids carbazomycin G (7) and carbazomycin H (8) was achieved by a highly convergent iron-mediated construction of the carbazole framework. Electrophilic substitution of the arylamine 15 using the iron co
Knoelker, Hans-Joachim,Froehner, Wolfgang,Reddy, Kethiri R.
p. 740 - 746
(2007/10/03)
Palladium-catalyzed total synthesis of the antibiotic carbazole alkaloids carbazomycin G and H
A highly efficient palladium-catalyzed synthesis affords carbazole-1,4-quinones which can be transformed directly into the carbazomycins G and H and are shown to represent precursors for several other biologically active carbazole alkaloids.
Knoelker, Hans-Joachim,Froehner, Wolfgang
p. 173 - 175
(2007/10/03)
Transition metal complexes in organic synthesis, Part 38. First total synthesis of carbazomycin G and H
The first total synthesis of the carbazole quinol alkaloids carbazomycin G and H has been achieved by a highly convergent synthesis using an iron-mediated construction of the carbazole nucleus as key-step.
Knoelker, Hans-Joachim,Froehner, Wolfgang
p. 4051 - 4054
(2007/10/03)
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