NOVEL (1,3-BUTADIEN-2-YL)METHYLAMINE DERIVATIVES AND PREPARATION METHOD THEREOF
The present invention provides a novel (1,3-butadien-2-yl)methylamine derivative and a preparation method thereof. The (1,3-butadien-2-yl)methylamine derivative having the 1,3-diene substituent at the alpha-position is an useful precursor in preparing various amine compounds having biochemical activities.
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Page/Page column 13
(2010/04/27)
Efficient preparation of 1,3-butadiene and cyclohexene derivatives possessing 2-aminomethyl group through indium-mediated 1,3-butadien-2-ylation
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Seomoon, Dong,Mo, Juntae,Kang, Dongjin,Eom, Dahan,Lee, Phil Ho
scheme or table
p. 503 - 506
(2010/09/04)
Synthetic method for the preparation of 2-aminomethyl-1,3-diene derivatives through indium-mediated 1,3-butadien-2-ylation of imines
An efficient method for the preparation of a variety of 2-aminomethyl-1,3-dienes was developed through the reaction of imines with organoindium reagent generated in situ from indium and 1,3-dibromo-2-butyne. Three-component reactions of aldehydes, amines,
Seomoon, Dong,Jaemyung A.,Lee, Phil Ho
supporting information; experimental part
p. 2401 - 2404
(2009/10/10)
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