115975-53-6Relevant articles and documents
FORMATION OF α-ENAMINOKETONES FROM α-AZIDOKETONES: AN ELIMINATION OF MOLECULAR NITROGEN FROM α-AZIDOKETONES.
Sant, Karey Van,South, Michael S.
, p. 6019 - 6020 (2007/10/02)
α-Enaminoketones are readily accessible through reaction of α-bromoketones with sodium azide followed by an elimination of molecular nitrogen.The reaction is base catalyzed and proceeds under relatively mild conditions.An anionic mechanism is proposed.