- The formation of benzoxacin-3-ones: Via intramolecular Nicholas reactions and synthesis of 8-membered heliannuols
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The γ-carbonyl cations generated from propargyl ether-Co2(CO)6 complexes undergo intramolecular Nicholas reactions to give dehydrobenzoxacin-3-one-Co2(CO)6 complexes in good yields. Reductive decomplexation and subsequent manipulation allows the synthesis of (±)-heliannuol K methyl ether and the formal syntheses of (±)-heliannuol K, (±)-heliannuol A, and (-)-heliannuol L.
- Green, James R.,St. Onge, Brent
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p. 7152 - 7155
(2021/08/30)
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- SYNTHESIS OF NEW N-ACYL DERIVATIVES OF DL-TRANS-1,2-AMINOCYCLOHEXANOL
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New amide derivatives of Dl-trans-1,2-aminocyclohexanol, with a potential action on the cardiovascular system, were obtained.Keywords: N-acyl derivatives of DL-trans-1,2-aminocyclohexanol, elemental analysis, 1H NMR.
- Pekala, Elzbieta,Gajewczyk, Leonard,Marona, Henryk
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p. 339 - 342
(2007/10/02)
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