Diels-Alder Cycloaddition of Azepino[4,5-b]indoles Towards Hydrocarbazole Derivatives and Related Heterocycles
An approach to hydrocarbazoles bearing an all-carbon quaternary center at C4a position was developed via a Br?nsted acid-initiated Diels-Alder cycloaddition/retro-aza-Michael addition cascade process from azepino[4,5-b]indoles and commercially available d
New strategy for the synthesis of substituted morpholines
(Chemical Equation Presented) A four-step synthesis of cis-3,5- disubstituted morpholines from enantiomerically pure amino alcohols is described. The key step in the synthesis is a Pd-catalyzed carboamination reaction between a substituted ethanolamine de
Leathen, Matthew L.,Rosen, Brandon R.,Wolfe, John P.
supporting information; experimental part
p. 5107 - 5110
(2009/10/23)
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