Sulfone Group as a Versatile and Removable Directing Group for Asymmetric Transfer Hydrogenation of Ketones
The sulfone functional group has a strong capacity to direct the asymmetric transfer hydrogenation (ATH) of ketones in the presence of [(arene)Ru(TsDPEN)H] complexes by adopting a position distal to the η6-arene ring. This preference provides a
Clarkson, Guy J.,Vyas, Vijyesh K.,Wills, Martin
p. 14265 - 14269
(2020/07/04)
A chemo-enzymatic synthesis of chiral secondary alcohols bearing sulfur-containing functionality
A facile method for the preparation of chiral secondary alcohols bearing a sulfur-containing functionality using a chemo-enzymatic approach is described, with the aid of baker's yeast and Candida Antarctica lipase B. A complete set of four stereoisomers o
Chen, Qihui,Wang, Ke,Yuan, Chengye
experimental part
p. 972 - 975
(2010/08/21)
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