Synthesis of N-acyl-β-aminoalcohols from N-acyloxazolidinones mediated by sodium azide
N-Acyl-β-aminoalcohols were obtained efficiently via a highly endocyclic cleavage of N-acyloxazolidinones mediated by sodium azide in methanol at 40°C.
Bouzide, Abderrahim,Sauvé, Gilles
p. 1961 - 1964
(2007/10/03)
CONTRASTERIC CARBOXIMIDE HYDROLYSIS WITH LITHIUM HYDROPEROXIDE
The use of lithium hydroperoxide for the highly regioselective hydrolysis of a range of carboximides is described.Numerous cases are provided where the regioselectivities exhibited by this reagent are dramatically different than the complementary reactions with hydroxide.
Evans, David A.,Britton, Thomas C.,Ellman Jon A.
p. 6141 - 6144
(2007/10/02)
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