cas 117186-74-0, (S)-N-(2-Benzoylphenyl)-2-pyrrolidinecarboxamide | Articles data ｜lookchem

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117186-74-0

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Synthesis of 5-arylpyrrolo[2,1-c][1,4]benzodiazepines under mild cyclodehydration conditions
The efficiency of a cyclodehydration reaction leading to benzodiazepinones is markedly improved by N-methylation of the amide link connecting the nucleophile and the electrophile, which is attributed to its favouring both the more reactive E-rotamer and the exit of the leaving group.
Legerén, Loreto,Domínguez, Domingo
experimental part
p. 2718 - 2722
(2010/05/02)

Enantiospecific synthesis of 5-phenylpyrrolo[2,1-c][1,4]benzodiazepines
Enantiomerically pure 5-phenylpyrrolo[2,1-c][1,4]benzodiazepines were synthesized starting from 2-aminobenzophenones and 2-amino-4-methoxyxanthone, using l-proline as a chiral building block.
Legerén, Loreto,Gómez, Eduardo,Domínguez, Domingo
scheme or table
p. 7174 - 7177
(2009/04/10)

ATTACHMENT OF THE CHIRAL REAGENT (S)-2N(N'-BENZYLPROLYL)-AMINOBENZOPHENONE TO A POLYMERIC CARRIER
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Nosova, N. A.,Lysova, L. A.,Ryzhov, M. T.,Vauchskii, Yu. P.,Istomina, V. P.,Anodina, N. M.
p. 1433 - 1436
(2007/10/02)

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1093987-01-9
N-{2-[hydroxy(phenyl)methyl]phenyl}-L-prolinamide

Chemical Properties

Melting Point: 95-97℃
Boiling Point: 551℃
Flash Point:210℃
Density: 1.219
Storage Temp.:2-8°C
PKA: 13.68±0.70(Predicted)
PSA: 61.69000
LogP: 3.58640

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