THE SYNTHESIS OF DESTOMYCIN C, A TYPICAL PSEUDO-TRISACCHARIDE OF DESTOMYCIN-GROUP ANTIBIOTICS
A synthesis is described of the pseudo-trisaccharide antibiotic, destomycin C, which contains orthoester and β-D-talopyranosidic linkages.A β-D-mannopyranosidic linkage was formed first in the presence of silver triflate in tetrahydrofuran.Glycosylidenati