TRIAZOLIUM CARBENE CATALYSTS AND PROCESSES FOR ASYMMETRIC CARBON-CARBON BOND FORMATION
Provided herein are chiral triazolium catalysts useful for asymmetric C-C bond formation and processes for their preparation. Also provided are synthetic reactions in which these catalysts are used, in particular, in asymmetric C-C bond formation.
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Page/Page column 28-29
(2012/02/02)
Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: Backbone fluorination improves selectivity
(Chemical Equation Presented) The catalytic asymmetric intermolecular Stetter reaction of heterocyclic aldehydes and nitroalkenes has been developed. We have identified a strong stereoelectronic effect on catalyst structure when a fluorine substituent is
DiRocco, Daniel A.,Oberg, Kevin M.,Dalton, Derek M.,Rovis, Tomislav
supporting information; experimental part
p. 10872 - 10874
(2009/12/03)
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