Stabilization and activation of dienolates with germanium and tin. Stero- and regioselective aldol reactions, regioselective coupling reactions, and regioselective synthesis of amino acid derivatives
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Yamamoto,Hatsuya,Yamada
p. 3118 - 3128
(2007/10/02)
Carbon-Carbon Bond Formation at the γ-position of Dienolates via the Palladium Catalysed Coupling of the Tin Masked Dienolates
The palladium catalysed coupling reaction of the tin masked dienolate (2) with organic halides takes place at the position substituted by tin, thereby providing a new method for C-C bond formation at the γ-position of dienolates.