Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols
A nickel-phosphine complex was found to be effective as the catalyst for the transformation of alcohols into β-enaminones, which was successively converted into γ-amino alcohols by a conventional reductant. The sequential transformation is equivalent to the carbon-nitrogen bond formation at the γ-position of saturated alcohols. Georg Thieme Verlag Stuttgart · New York.
Ueno, Satoshi,Usui, Kazumi,Kuwano, Ryoichi
p. 1303 - 1307
(2011/07/08)
Nickel-catalyzed formation of a carbon-nitrogen bond at the β position of saturated ketones
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Ueno, Satoshi,Shimizu, Ryosuke,Kuwano, Ryoichi
supporting information; experimental part
p. 4543 - 4545
(2009/10/30)
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