CHIRAL THIOPHENE DIOXIDES AND THIOPHENE S,N-YLIDES AS DIENES FOR ASYMMETRIC DIELS-ALDER APPLICATION
2-Menthyltrihalothiophene S,S-dioxides are efficient asymmetric dienes in Diels-Alder reactions with dienophiles to give regio- and stereoisomerically pure adducts.Thus styrene, allyl alcohol, methyl acrylate and acrylamide give solely one adduct while fl
Dillen, Jan L.M.,Meth-Cohn, Otto,Moore, Clive,van Rooyen, Petrus H.
p. 3127 - 3138
(2007/10/02)
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