- Ozonolysis of Tetrasubstituted Ethylenes, Cycloolefins, and Conjugated Dienes on Polyethylene
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Ozonolyses of four tetrasubstituted ethylenes (7a-d), of two medium-sized cycloolefins (10a,b), and of norbornene (14) on polyethylene gave the corresponding ozonides, which could not be obtained by ozonolyses in solution.Ozonolyses of three conjugated dienes (25a,b,28) on polyethylene gave the corresponding diozonides, as the first examples of this class of ozonides.The thermal decomposition of some of the ozonides has been studied.
- Griesbaum, Karl,Volpp, Willi,Greinert, Reinhard,Greunig, Hans-Joachim,Schmid, Jurgen,Henke, Henning
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p. 383 - 389
(2007/10/02)
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- Acyloxy-1,2,4-trioxolanes by Dry Ozonolyses of Vinylesters on Polyethylene
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By dry ozonolyses on polyethylene, the vinylic esters 5a-5e afforded the corresponding ozonides 8a-8e, while 5f gave ozonide 8e.Ozonide 8a gave among other products 16 and 17 by thermal decomposition, and 21 by decomposition on silica gel. - Key Words: Acyloxy-1,2,4-trioxolanes / Ozonolysis, dry / Polyethylene / Vinylic esters
- Griesbaum, Karl,Volpp, Willi,Huh, Tae-Seong,Jung, In Chan
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p. 941 - 944
(2007/10/02)
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