Gold-catalyzed [4C+2C] cycloadditions of allenedienes, including an enantioselective version with new phosphoramidite-based catalysts: Mechanistic aspects of the divergence between [4C+3C] and [4C+2C] pathways
Gold(I) complexes featuring electron acceptor ligands such as phosphites and phosphoramidites catalyze the [4C+2C] intramolecular cycloaddition of allenedienes. The reaction is chemo- and stereoselective, and provides trans-fused bicyclic cycloadducts in
Alonso, Isaac,Trillo, Beatriz,Lopez, Fernando,Montserrat, Sergi,Ujaque, Gregori,Castedo, Luis,Lledos, Agusti,Mascarenas, Jose L.
supporting information; experimental part
p. 13020 - 13030
(2009/12/08)
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