Synthese et stereochimie de perhydrocyclopentafurannones-3-cis et perhydrocyclopentafurannols-3-cis
Synthetic route to new cis-perhydrocyclopentafuran-3-ones and cis-perhydrocyclopentafuran-3-ols is described.Their configurations and conformations were inferred by 1H and 13C nmr spectroscopy.A certain rigidity is associated with the bond common to the two fused ring.The conformation of tetrahydrofuran-3-one ring appears to be composite of the Cs and C2 forms depending on the C-2 substitution.
Dolmazon, Rene
p. 751 - 757
(2007/10/02)
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