Imidazol-2-ylidene-4-olate: An anionic N-heterocyclic carbene pre-programmed for further derivatization
The 4-hydroxyimidazolium salt, readily prepared in two steps by acylation of a formamidine and quaternization of the second nitrogen, affords, after deprotonation, the anionic imidazol-2-ylidene-4-olate, which can be complexed to a transition metal and st
Benhamou, Laure,Cesar, Vincent,Gornitzka, Heinz,Lugan, Noel,Lavigne, Guy
supporting information; experimental part
p. 4720 - 4722
(2010/01/15)
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