Rh(I)-catalyzed decarboxylative transformations of arenecarboxylic acids: Ligand- and reagent-controlled selectivity toward hydrodecarboxylation or heck-mizoroki products
(Chemical Equetion Presentation) A Rh(I)-based catalyst system has been developed to promote three types of decarboxylative transformations of arenecarboxylic acids: (1) hydrodecarboxylation, (2) Heck-Mizoroki olefination, and (3) conjugate addition. Scopes of reactions (1) and (2) were studied, and the ligand and reagent dependence of selectivity was explored.
Sun, Zhong-Ming,Zhang, Jing,Zhao, Pinjing
supporting information; experimental part
p. 992 - 995
(2010/06/16)
Rhodium-mediated decarboxylative conjugate addition of fluorinated benzoic acids: stoichiometric and catalytic transformations
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Sun, Zhong-Ming,Zhao, Pinjing
supporting information; experimental part
p. 6726 - 6730
(2009/12/26)
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