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9,9'-spirobi[fluoren]-2-amine is a chemical compound characterized by its unique spiro-structured backbone, formed by two fluorene units connected through a spiro carbon atom. 9,9'-spirobi[fluoren]-2-amine is recognized for its excellent thermal stability, high glass transition temperatures, and unique optical properties, including high photoluminescence efficiency and good charge-transport characteristics. These features render 9,9'-spirobi[fluoren]-2-amine a valuable monomer in the synthesis of innovative organic materials, particularly for applications in organic electronics, photovoltaics, and optoelectronics.

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  • 118951-68-1 Structure
  • Basic information

    1. Product Name: 9,9'-spirobi[fluoren]-2-amine
    2. Synonyms: 9,9'-spirobi[fluoren]-2-amine;9,9'-Spirobi[9H-fluoren]-2'-amine;2-aminospirobifluorene;[9,9']spirobifluoren-2-yiamine
    3. CAS NO:118951-68-1
    4. Molecular Formula: C25H17N
    5. Molecular Weight: 331.40918
    6. EINECS: -0
    7. Product Categories: N/A
    8. Mol File: 118951-68-1.mol
  • Chemical Properties

    1. Melting Point: 233 °C
    2. Boiling Point: 536.9±29.0 °C(Predicted)
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: 1.32±0.1 g/cm3(Predicted)
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. PKA: 3.87±0.20(Predicted)
    10. CAS DataBase Reference: 9,9'-spirobi[fluoren]-2-amine(CAS DataBase Reference)
    11. NIST Chemistry Reference: 9,9'-spirobi[fluoren]-2-amine(118951-68-1)
    12. EPA Substance Registry System: 9,9'-spirobi[fluoren]-2-amine(118951-68-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 118951-68-1(Hazardous Substances Data)

118951-68-1 Usage

Uses

Used in Organic Electronics Industry:
9,9'-spirobi[fluoren]-2-amine is used as a monomer for synthesizing novel organic materials due to its excellent thermal stability and high glass transition temperatures, which are crucial for the development of robust electronic devices.
Used in Photovoltaics:
In the photovoltaics industry, 9,9'-spirobi[fluoren]-2-amine is utilized as a monomer to create materials with potential applications in solar cells, capitalizing on its ability to enhance the efficiency and performance of these energy-harvesting devices.
Used in Optoelectronics:
9,9'-spirobi[fluoren]-2-amine is employed as a key component in the optoelectronics field, where its unique optical properties, such as high photoluminescence efficiency, are harnessed for the development of advanced light-based electronic devices.
Used in the Development of Organic Light-Emitting Diodes (OLEDs):
9,9'-spirobi[fluoren]-2-amine is used as a building block in the creation of organic light-emitting diodes (OLEDs), taking advantage of its high photoluminescence efficiency and good charge-transport characteristics to improve the performance and reliability of these display technologies.
Used in Research and Development of New Functional Materials:
9,9'-spirobi[fluoren]-2-amine serves as a promising candidate for research and development efforts aimed at designing and developing new functional materials with tailored properties for various high-tech applications.

Check Digit Verification of cas no

The CAS Registry Mumber 118951-68-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,8,9,5 and 1 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 118951-68:
(8*1)+(7*1)+(6*8)+(5*9)+(4*5)+(3*1)+(2*6)+(1*8)=151
151 % 10 = 1
So 118951-68-1 is a valid CAS Registry Number.

118951-68-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-amino-9,9'-spirobifluorene

1.2 Other means of identification

Product number -
Other names 2-aminospirobifluorene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:118951-68-1 SDS

118951-68-1Relevant articles and documents

Synthesis, Photochromism, and Thermal Stability of Two New Diarylethenes Based On Spirobifluorene

Li, Caihua,Zeng, Heping

, p. 1706 - 1714 (2016)

Two novel spirobifluorene-diarylethenes compounds with furan (9a) and thiophen (8a) as heterocyclic aryl groups were successfully synthesized, and their structures were fully characterized with FTIR, NMR, mass spectra (MS), and elemental analysis. Their photochromic properties were examined. The results indicated that they showed good photochromic behaviors in hexane and acetonitrile. The fluorescence emission was quenched along with the photochromism from open ring to closed ring. Large fluorescence emission blue-shift was clearly observed in polar solvents. Furthermore, the thermal stability of 8a and 9a was greatly improved by introducing spirobifluorene group into the molecules. The 5% loss weight temperature of 9a was 59°C higher than that of 10a without spirobifluorene.

Novel compounds for organic electroluminescent device

-

, (2017/07/23)

Provided is a compound which is represented by chemical formula 1, and is used to manufacture an organic electroluminescent device. According to the present invention, the compound has high hole mobility, high thermal stability, a high band gap energy, a

Synthesis and characterization of heteroatom-bridged bis-spirobifluorenes for the application of organic light-emitting diodes

Wu, Cheng-Lung,Chen, Chao-Tsen,Chen, Chin-Ti

supporting information, p. 2114 - 2117 (2014/05/06)

Pure 2-iodo-9,9′-spirobifluorene was synthesized by an efficient method without troublesome iodination of 9,9-spirobifluorene (SP) or the Sandmeyer reaction of 2-amino-9,9′-spirobifluorene. A series of main group element-bridged bis-9,9′-spirobifluorene d

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