2-Aryl propionamides via 1,4-aryl radical migration from N-arylsulfonyl-2-bromopropionamides
Reaction of N-alkyl-N-arylsulfonyl-2-halo-propionamides with pentamethyldiethylenetriamine and either CuBr or CuCl leads to 2-aryl propionamides via initial radical generation, 1,4-aryl migration with loss of SO2 and reduction of the intermedia
Clark, Andrew J.,Coles, Stuart R.,Collis, Alana,Fullaway, David R.,Murphy, Nicholas P.,Wilson, Paul
experimental part
p. 6311 - 6314
(2010/01/18)
1,4-Aryl migration under copper(I) atom transfer conditions
Reaction of N-alkyl-N-(trichloroacetyl)arylsulfonamides with CuCl/amines leads to N-alkyl-N-(dichloroacetyl)-arylsulfonamides via reduction or N-alkyl-aryldichloroacetamides via 1,4-aryl migration with loss of SO2. The ratio of reduction to ary
Clark, Andrew J.,Coles, Stuart R.,Collis, Alana,Debure, Thomas,Guy, Collette,Murphy, Nicholas P.,Wilson, Paul
experimental part
p. 5609 - 5612
(2011/02/24)
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