PARA-ALKYL-SUBSTITUTED PHENYLCYCLOPROPANES IN REACTION WITH DINITROGEN TETROXIDE
The reaction of para-alkyl-substituted phenylcyclopropanes with dinitrogen tetroxide was studied.In solvents with various polarities at -30 deg C dinitrogen tetroxide only reacts with the three-carbon ring.Here the initially formed adducts are only stable at low temperatures; with increase in temperature they are converted into p-alkylcinnamaldehydes and 5-(p-alkylphenyl)isoxazolines.
Smirnova, M. M.,Geiderikh, A. V.,Mochalov, S. S.,Shabarov, Yu. S.
p. 1070 - 1075
(2007/10/02)
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