Selective Cis-Trans Isomerization of a Tetraene via an Allene Intermediate: Geometric Isomerism via an sp2 to sp2 Sigmatropic Hydrogen Shift and Kinetic Isotope Effect Studies
A kinetic investigation in the unlabeled and deuterium-labeled series of the sigmatropic hydrogen shift of vinylallene 5 to trienes 7 plus 8 and the sigmatropic hydrogen shift of dienallene 6 to tetraenes 9 plus 10 has been completed.The resul
Palenzuela, J. Antonio,Elnagar, Hassan Y.,Okamura, William H.
p. 1770 - 1773
(2007/10/02)
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