119365-15-0

Basic information

• Product Name: 5H-Cyclopenta[c]pyridin-5-ol,6,7-dihydro-7-methyl-,(5R,7S)-rel-(-)-(9CI)
• Synonyms: 5H-Cyclopenta[c]pyridin-5-ol,6,7-dihydro-7-methyl-,(5R,7S)-rel-(-)-(9CI)
• CAS NO: 119365-15-0
• Molecular Formula: C9H11NO
• Molecular Weight: 149.19
• Product Categories: PYRIDINE
• Mol File: 119365-15-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5H-Cyclopenta[c]pyridin-5-ol,6,7-dihydro-7-methyl-,(5R,7S)-rel-(-)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 5H-Cyclopenta[c]pyridin-5-ol,6,7-dihydro-7-methyl-,(5R,7S)-rel-(-)-(9CI)(119365-15-0)
• EPA Substance Registry System: 5H-Cyclopenta[c]pyridin-5-ol,6,7-dihydro-7-methyl-,(5R,7S)-rel-(-)-(9CI)(119365-15-0)

Safety Data

• Hazardous Substances Data: 119365-15-0(Hazardous Substances Data)

Upstream product

• 184827-08-5 3-bromo-4-(1'-hydroxy-3'-butenyl)pyridine 
• 70201-43-3 3-bromo-pyridine-4-carbaldehyde 
• 626-55-1 3-Bromopyridine 
• 872-85-5 pyridine-4-carbaldehyde 

Relevant articles and documents

Pyridine radicals in synthesis. Part 3: Cyclopentannulation of pyridine via the 3-pyridyl radical and a formal synthesis of (±)-oxerine

The allylation and propargylation of 3-bromo-4-formylpyridine under zinc-mediated Barbier conditions is described. The homoallylic alcohols produced are cyclised via the derived 3-pyridyl radical to give cyclopentannulated pyridines. One of these bicyclic compounds is converted into an advanced intermediate in a previous synthesis of the monoterpene alkaloid (±)-oxerine. (C) 2000 Elsevier Science Ltd.

Pyridine radicals in synthesis: A formal total synthesis of (±)-oxerine

The cyclisation of pyridine radicals derived from 3-bromo-4-substituted pyridines carrying both alkene and alkyne groups in the 4-substituent to give is described. The cyclopentano[c]pyridine skeleton formed by cyclisation is found in many monoterpene alkaloids and a short synthesis of a late intermediate in the previous synthesis of (±)-oxerine is presented.