119771-49-2Relevant articles and documents
Synthesis of Spiro Indolin-2-one Derivatives
El-Ahl, Abdel Asis S.,Afeefy, Hussein,Metwally, Mohamed Abbas
, p. 201 - 222 (2007/10/02)
The reactions of active methylene compounds and hydrazine with (2-oxoindolin-3-ylidene)-malononitrile and -acetophenone in ethanol/piperidine have been studied.Both substances gave Michael-type adducts followed by cyclization.The structures of the products were determined from the results of elemental analysis, IR, 1H-NMR and mass spectra.
Syntheses with Nitriles, LXXXII. - On Spiro and Indene-propellanes - Adducts of 2-(Dicyanomethylene)-1,3-indandione with 1,3-Dicarbonyl Compounds
Dworczak, Renate,Sterk, Heinz,Kratky, Christoph,Junek, Hans
, p. 1323 - 1328 (2007/10/02)
The reactivity of 2-(dicyanomethylene)-1,3-indandione (1) towards 1,3-dicarbonyl compounds depends strongly on the nature of the CH acidic component.While the reaction with dimedone yields a spiro (2), indene-propellanes (3) are formed with acetoacetic esters.Adducts of acetylacetone and benzoylacetic acid ethyl ester to 1 have been identified as spiro- (4).The propellane structure 3 is proven by X-ray analysis.Adducts 6 of CH acidic components with 3-(dicyanomethylene)-2-indolones 5 are used for reference measurements. - Key Words: Nitriles / Spiro compounds / Propellanes / Indan derivatives / Cycloaddition