Condensation of dimethyl malonate with benzal-4-acetyIanilines: A chemoselective reaction
Dimethyl malonate has reacted chemoselectively with carbon- nitrogen double bond of benzal-4-acetylanilines (1-8) leaving the carbon-oxygen double bond, considered to be more reactive, intact under reaction conditions, leading to the formation of mono addition-elimination products rather than bis attack at both the double bonds, even when the reaction has been carried out with two moles of dimethyl malonate.
Sidhu, Anjali,Rai, Mangat
experimental part
p. 735 - 736
(2009/12/24)
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