120085-89-4Relevant articles and documents
A straightforward oxidation of dienones to 2-acetylfurans by selenium dioxide
No, Zaesung,Chae, Yung Bog,Shin, Chan Jae,Chung, Yongseog
, p. 6191 - 6194 (2007/10/03)
Direct oxidation of (E)-4-(6-substituted-1-cyclohexenyl)-3-buten-2-ones (4a-7a) by selenium dioxide afforded 2-acelyltetrahydrobenzofurans (4b-7b) in moderate to good yields. An inverse, stepwise [2+4] cycloaddition mechanism of the intermediate formation was proposed from conformational and electronic requirements of conjugated dienones and solvent effects of SeO2 oxidation.
Intramolecular Cycloadditions of Mesionic Carbonyl Ylides with Alkynes. Synthesis of 5,6-Dihydro-4H-cyclopenta- and 4,5,6,7-Tetrahydrobenzofuran Derivatives
Maier, Martin E.,Schoeffling, Baerbel
, p. 1081 - 1088 (2007/10/02)
Intramolecular cycloaddition reactions of acetylenic isomuenchnones, formed in situ by rhodium acetate catalyzed decomposition of N-(diazoacetyl)-N-methylalkynamide derivatives 16a-c, 18c, and 18d have been studied.The intermediate cycloadducts fragmentate spontaneously under the reaction conditions (110 deg C) to afford the annulated furans 19a-c, 20c, and 20d. - Keywords: Carbonyl ylides; Furans; Intramolecular cycloadditions; Isomuenchnones