cas 120133-99-5, 4-Oxazolecarboxylicacid,4,5-dihydro-4,5-dimethyl-,methylester,(4S-trans)- | Articles data ｜lookchem

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120133-99-5

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Fluoride-catalyzed aldol-type reactions of α-isocyano esters producing 2-oxazoline derivatives
An α-isocyano ester underwent the fluoride-catalyzed aldol-type reaction with an aldehyde to afford a 2-oxazoline derivative.
Ito, Yoshihiko,Higuchi, Noriko,Murakami, Masahiro
p. 91 - 93
(2007/10/03)

ASYMMETRIC SYNTHESIS OF β-HYDROXY-α-ALKYLAMINO ACIDS BY ASYMMETRIC ALDOL REACTION OF α-ISOCYANOCARBOXYLATES CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-GOLD(I) COMPLEXES
Aldol reaction of methyl α-isocyanocarboxylates (CNCH(R)COOMe: R = H, Me, Et, i-Pr) with benzaldehyde or acetaldehyde in the presence of 0.5-1.0 molpercent of a chiral (aminoalkyl)ferrocenylphosphine-gold(I) complex gave optically active 4-methoxycarbonyl
Ito, Yoshihiko,Sawamura, Masaya,Shirakawa, Eiji,Hayashizaki, Keiichi,Hayashi, Tamio
p. 5253 - 5262
(2007/10/02)

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Chemical Properties

Boiling Point: 184.3±50.0 °C(Predicted)
Density: 1.16±0.1 g/cm3(Predicted)
PKA: 2.78±0.60(Predicted)
PSA: 47.89000
LogP: -0.19930

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