120225-74-3

Basic information

• Product Name: tert-Butyl 4-(Cyanomethyl)cinnamate
• Synonyms: 3-[4-(Cyanomethyl)phenyl]-2-Propenoic acid1,1-Dimethylethyl Ester;tert-Butyl 4-(Cyanomethyl)cinnamate;(E)-tert-butyl 3-(4-(cyanoMethyl)phenyl)acrylate;tert-Butyl 3-(4-(cyanomethyl)phenyl)acrylate
• CAS NO: 120225-74-3
• Molecular Formula: C₁₅H₁₇NO₂
• Molecular Weight: 243.31
• Product Categories: All Aliphatics;Aliphatics;Aromatics
• Mol File: 120225-74-3.mol

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• Solubility: Dichloromethane, Ethyl Acetate, Methasnol
• CAS DataBase Reference: tert-Butyl 4-(Cyanomethyl)cinnamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl 4-(Cyanomethyl)cinnamate(120225-74-3)
• EPA Substance Registry System: tert-Butyl 4-(Cyanomethyl)cinnamate(120225-74-3)

Safety Data

• Hazardous Substances Data: 120225-74-3(Hazardous Substances Data)

Usage

Chemical Properties

Light Yellow Solid

Upstream product

• 1663-39-4 tert-Butyl acrylate 
• 16532-79-9 4-Bromophenylacetonitrile 

Downstream Products

• 120225-79-8 tert-butyl 3-<4-(2-aminoethyl)phenyl>propionate 
• 120225-78-7 p-(2-t-butoxycarbonyl-ethyl)-phenyl-acetonitrile 
• 120225-76-5 2-<<4-<2-(tert-butoxycarbonyl)etyl>phenethyl>amino>-2',3'-O-isopropylideneadenosine-5'-N-ethylcarboxamide 
• 124431-80-7 2-p-(2-carboxyethyl)phenethylamino-5'-N-ethylcarboxamidoadenosine hydrochloride 
• 127258-46-2 2-<<4-(2-carbomethoxyetyl)phenethyl>amino>adenosine-5'-N-ethylcarboxamide hydrochloride 

Relevant articles and documents

Encaging palladium(0) in layered double hydroxide: A sustainable catalyst for solvent-free and ligand-free Heck reaction in a ball mill

In this paper, the synthesis of a cheap, reusable and ligand-free Pd catalyst supported on MgAl layered double hydroxides (Pd/MgAl-LDHs) by co-precipitation and reduction methods is described. The catalyst was used in Heck reactions under highspeed ball milling (HSBM) conditions at room temperature. The effects of milling-ball size, milling-ball filling degree, reaction time, rotation speed and grinding auxiliary category, which would influence the yields of mechanochemical Heck reactions, were investigated in detail. The characterization results of XRD, ICP-MS and XPS suggest that Pd/MgAl-LDHs have excellent textural properties with zero-valence Pd on its layers. The reaction results indicate that the catalyst could be utilized in HSBM systems to afford a wide range of Heck coupling products in satisfactory yields. Furthermore, this catalyst could be easily recovered and reused for at least five times without significant loss of catalytic activity.

2-(Arylalkylamino)adenosin-5'-uronamides: A New Class of Highly Selective Adenosine A2 Receptor Ligands

The synthesis and receptor-binding profiles at adenosine receptor subtypes for a series of 2-(arylalkylamino)adenosin-5'-uronamides is described.Halogenated 2-phenethylamino analogues such as 3e show greater than 200-fold selectivity for the A2 receptor s