FACILE CATALYTIC METHODS FOR INTERMOLECULAR GENERATION OF ALLYLIC OXONIUM YLIDES AND THEIR STEREOSELECTIVE -SIGMATROPIC REARRANGEMENT
Allylic oxonium ylides, generated by rhodium(II) acetate-catalyzed decomposition of diazo carbonyl compounds in the presence of allyl methyl ethers, undergo the -sigmatropic rearrangement with a high degree of diasteroselectivity.
Doyle, Michael P.,Bagheri, Vahid,Harn, Nancy K.
p. 5119 - 5122
(2007/10/02)
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