Enamine-lminium ion nazarov cyclization of α-ketoenones
[Chemical equaction presented] The mono-triflate salts of some chiral nonracemic 1,2-diamines react with α-ketoenones in a stoichiometric reaction to form products of the Nazarov cyclization in high enantiomeric ratios. The mechanism appears to involve rearrangement of an enamine-iminium ion.
Bow, William F.,Basak, Ashok K.,Jolit, Anais,Vicic, David A.,Tius, Marcus A.
supporting information; experimental part
p. 440 - 443
(2010/04/24)
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