Cross-couplings between benzylic and aryl halides on water : Synthesis of diarylmethanes
A remarkably simple entry to unsymmetrical diarylmethanes has been developed that relies on an in situ organozinc-mediated, palladium-catalyzed cross-coupling. Thus, by mixing a benzyl and aryl halide together in the presence of Zn metal and a Pd catalyst, diarylmethanes are formed at room temperature without assistance by a surfactant; hence, on water .
Duplais, Christophe,Krasovskiy, Arkady,Wattenberg, Alina,Lipshutz, Bruce H.
supporting information; experimental part
p. 562 - 564
(2010/05/01)
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