Stereoselective synthesis of a monocyclic peloruside A analogue
Chemical Equation Presentation The stereoselective synthesis of the monocyclic peloruside A analogue 4 has been achieved, following a new efficient approach for the introduction of the side chain, involving a late-stage addition of vinyl lithium species 7a to aldehyde 8. Further key steps are a highly diastereoselective allyltitanation reaction and a RCM-based macrocyclization.
Wulischleger, Christoph W.,Gertsch, Juerg,Altmann, Karl-Heinz
supporting information; experimental part
p. 1120 - 1123
(2010/06/13)
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